WW2 Aircraft Performance (wwiiaircraftperformance.com) - Has primary source data in droves for the Spitfire Mk.V and a good bit on the A6M2 and A6M5.
Spitfire Va:
Flaps Up - Gear Up around 76 mph (Indicated Air Speed)
Flaps Down Gear Down around 69 mph (Indicated)
Wing Loading : 25.3 lbs/ft^2
A6M2:
Kinda all over the place with regards to in air testing - Navy says 74mph clean, 61 mph dirty (Indicated) but Air Force has 65mph clean and 59ph dirty (Indicated). Most wartime testing is pretty inaccurate so take these with a grain of salt.
Wing Loading : 22.77 lbs/ft^2 [5500 Gross Weight (Average between several tests and MGW) / 241.5 ft^2 (Wing Area)
Wing loading is definetly lower for the A6M2 so instantaneous turn is well in its favor.
I think the A6M2 definetely has the edge in terms of low speed and aerodynamic turning, however its low weight and engine power did reduce its ability to retain energy. A Spitfire on the tail of an A6M2, IMO, will not be able to stay on its tail, and if the Spitfire is caught at a low enough speed I think it is in a decisively dangeous position. However, medium to high speeds is obviously where the two switch.